Tran Nguyen Phuong Lan * , Meng-Jiy Wang , Yi-Hsu Ju and Jhy-Chern Liu

* Corresponding author (tnplan@ctu.edu.vn)

Main Article Content

Abstract

Commercial production of biodiesel mainly uses refined edible oil as the feedstock which constitutes about 70% to 85% of the overall cost of biodiesel. Finding cheap and abundant new feedstock for producing biodiesel is necessary. The use of non-edible oil such as waste cooking oil and algae oil may help in reducing the production cost of biodiesel. In this study, 5 wet sludge samples were collected from a wide spectrum of industries in Taiwan and which were treated by subcritical water to enhance the amount of their extractable lipids. Reaction temperature was found to be the most important factor in increasing the extractable neutral lipids (2 to 3.5 times) which can be esterified with methanol to produce biodiesel. The economic potential of using activated sludge as feedstock for biodiesel production in Taiwan was discussed.
Keywords: Activated sludge, biodiesel, economic feasibility, hydrolysis, subcritical water

Article Details

References

Alhassan, Y., Kumar, N., Bugaje., I.M., Pali, H.S., Kathkar, P., 2014. Co-solvents transesterification of cotton seed oil into biodiesel: Effects of reaction conditions on quality of fatty acids methyl esters. Energy Conversion and Management. 84: 640-648.

Boocock, D.G.B., Konar, S.K., Leung A., Ly, L.D., 1992. Fuels and chemicals from sewage sludge: 1. The solvent extraction and composition of a lipid from a raw sewage sludge. Fuel. 71: 1283-1289.

Dufreche, S., Hernandez, S.R., French, T., Sparks, D., Zappi, M., Alley, E., 2007. Extraction of lipids from municipal wastewater plant microorganisms for production of biodiesel. Journal of the American Oils and Chemists’ Society. 84: 181-187.

Fujii, T., Khuwijitjaru, P., Kimura, Y., Adachi, S., 2006. Decomposition kinetics of monoacyl glycerol and fatty acid in subcritical water under temperature-programmed heating conditions. Food Chemistry. 94: 341-347.

Huang, Y.H, Wu, J.H., 2008. Analysis of biodiesel promotion in Taiwan. Renewable & Sustainable Energy Reviews. 12: 1176-1186.

Huynh, L.H., Tran-Nguyen, P.L., Ho, Q.P., Ju, Y.H., 2012. Catalyst-free fatty acid methyl ester production from wet activated sludge under subcritical water and methanol condition. Bioresource Technology. 123: 112-116.

Industrial waste report and management system, Industrial waste report in 2012, http://waste.epa.gov.tw/prog/IndexFrame.asp?Func=5 (accessed June 2013).

Jarde, E., Mansuy, L., Faure, P., 2005. Organic markers in the lipidic fraction of sewage sludges. Water Research. 39: 1215-1232.

King, J.W., Holliday, R.L., List, G. R., 1999. Hydrolysis of soybean oil. in a subcritical water flow reactor. Green Chemistry. 1: 261-264.

Kusdiana, D., Saka, S., 2001. Kinetics of transesterification in rapeseed oil to biodiesel fuel as treated in supercritical methanol. Fuel. 80: 693-698.

Kusdiana, D., Saka, S., 2004. Two-step preparation for catalyst-free biodiesel fuel production. Applied Biochemistry and Biotechnology. 115: 781-791.

Lee, D.J., 2007. Wastewater Sludge: A Global Overview of the Current Status and Future prospects, Spinosa, L. (Ed.) Second Edition. IWA Publishing Ltd., 98 pages.

Mondala, A., Liang, K., Toghiani, H., Hernandez, R., French, T., 2009. Biodiesel production by in situ transesterification of municipal primary and secondary sludges. Bioresource Technology. 100: 1203-1210.

Revellame, E., Hernandez, R., French, W., Holmes, W., Alley, E., Callahan II, R., 2011. Production of biodiesel from wet activated sludge. Journal of Chemical Technology and Biotechnology. 86: 61-68.

Saka, S., Kusdiana, D., 2001. Biodiesel fuel from rapeseed oil as prepared in supercritical methanol. Fuel. 80: 225-231.

Scott, G.M., Smith, A., Abubakr, S., 1995. Sludge characteristics and disposal alternatives for the pulp and paper industry. In: Proceedings of the 1995 international environmental conference. Recycling Symposium, TAPPI Proceedings, pp 269–279.

Siddiquee, M.N., Rohani, S., 2011. Lipid extraction and biodiesel production from municipal sewage sludge: A review. Renewable & Sustainable Energy Reviews. 15: 1067-1072.

Tran-Nguyen, P.L., Go, A.W, Huynh, L.H., Ju, Y.H., 2013. A study on the mechanism of subcritical water treatment to maximize extractable cellular lipids. Biomass and Bioenergy. 59: 532-539.

Tran-Nguyen, P.L., Go, A.W., Ismadji, S., Ju, Y.H., 2015. Transesterification of activated sludge in subcritical solvent mixture. Bioresource Technology, 197: 30-36.

Tsai, W.T., Lin, C.C., Yeh, C.W., 2007. An analysis of biodiesel fuel from waste edible oil in Taiwan. Renewable & Sustainable Energy Reviews. 11: 838-857.

Tsigie, Y.A., Huynh, L.H., Ahmed, I.N., Ju, Y.H., 2012. Maximizing biodiesel production from Yarrowia lipolytica Po1g biomass using subcritical water pretreatment. Bioresource Technology. 111: 201-207.

Tsigie, Y.A., Huynh, L.H., Tran-Nguyen, P.L., Ju, Y.H., 2013. Catalyst-free biodiesel preparation from wet Yarrowia lipolytica Po1g biomass under subcritical condition. Fuel Processing Technology. 115: 50-56.

Tyagi, V.K., Lo, S.L., 2013. Sludge: A waste or renewable source for energy and resources recovery? Renewable & Sustainable Energy Reviews. 25: 708-728.

Yeboah, A., Naanwaab, C., Yeboah, O., Owens, J., Bynum, J., 2013. Economic Feasibility of Sustainable High Oilseed-Based Biofuel production: The case for Biodiesel in North Carolina. International Food and Agribusiness Management Review. 16: 41-66.

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