Nguyen Minh Nhut * , Tran Ba Huy , Nguyen Khoi Nghia and Dang Huynh Giao

* Corresponding author (nmnhut@ctu.edu.vn)

Main Article Content

Abstract

Dibenzofuran (DBF) has been considered an environmental risk due to its high toxicity and risks to human health and ecosystems. Among wastewater treatment technologies, the adsorption process has emerged as a potential solution to remove organic pollutants efficiently, including dibenzofuran, in wastewater. The study aims to investigate the feasibility of sugarcane bagasse-based biochar for DBF removal through adsorption. Biochar characteristics showed a high specific surface area of up to 498.97 m2/g and abundant functional groups on the material surface, resulting in high removal performance of DBF with average adsorption efficiency and adsorption capacity reaching maximum values of 98.43% and 96.77 mg/g, respectively. The optimum parameters were suggested for DBF removal: pyrolysis temperature of 700oC, contact time of 50 min, biochar dosage of 0.5 g/L, and DBF concentration of 40 mg/L. Furthermore, the results of adsorption kinetics and adsorption isotherms indicated that the adsorption process benefits DBF removal. Pseudo-second-order model and Langmuir model can describe the DBF removal process due to the best fit to experimental data (R2 > 0.98). Based on these findings, sugarcane bagasse-based biochar could be utilized efficiently to remove DBF from wastewater.

Keywords: Adsorption, biochar, dibenzofuran, pyrolysis, sugarcane bagasse, wastewater treatment

Article Details

References

Bai, L., Su, X., Feng, J., & Ma, S. (2021). Preparation of sugarcane bagasse biochar/nano-iron oxide composite and mechanism of its Cr (VI) adsorption in water. Journal of Cleaner Production, 320, 128723. https://doi.org/https://doi.org/10.1016/j.jclepro.2021.128723

Baran, A., Urbaniak, M., Szara, M., & Tarnawski, M. (2021). Concentration of dioxin and screening level ecotoxicity of pore water from bottom sediments in relation to organic carbon contents. Ecotoxicology, 30(1), 57-66. https://doi.org/10.1007/s10646-020-02318-w

Creamer, A. E., Gao, B., & Zhang, M. (2014). Carbon dioxide capture using biochar produced from sugarcane bagasse and hickory wood. Chemical Engineering Journal, 249, 174-179. https://doi.org/https://doi.org/10.1016/j.cej.2014.03.105

Ding, W., Dong, X., Ime, I. M., Gao, B., & Ma, L. Q. (2014). Pyrolytic temperatures impact lead sorption mechanisms by bagasse biochars. Chemosphere, 105, 68-74. https://doi.org/https://doi.org/10.1016/j.chemosphere.2013.12.042

Divband Hafshejani, L., Hooshmand, A., Naseri, A. A., Mohammadi, A. S., Abbasi, F., & Bhatnagar, A. (2016). Removal of nitrate from aqueous solution by modified sugarcane bagasse biochar. Ecological Engineering, 95, 101-111. https://doi.org/https://doi.org/10.1016/j.ecoleng.2016.06.035

Dopico, M., & Gómez, A. (2015). Review of the current state and main sources of dioxins around the world. Journal of the Air & Waste Management Association, 65(9), 1033-1049.

El-Khaiary, M. I., Malash, G. F., & Ho, Y.-S. (2010). On the use of linearized pseudo-second-order kinetic equations for modeling adsorption systems. Desalination, 257(1), 93-101. https://doi.org/https://doi.org/10.1016/j.desal.2010.02.041

Förstner, U., Hollert, H., Brinkmann, M., Eichbaum, K., Weber, R., & Salomons, W. (2016). Dioxin in the Elbe river basin: policy and science under the water framework directive 2000–2015 and toward 2021. Environmental Sciences Europe, 28, 1-25.

Gan, C., Liu, Y., Tan, X., Wang, S., Zeng, G., Zheng, B., & Liu, W. (2015). Effect of porous zinc–biochar nanocomposites on Cr(vi) adsorption from aqueous solution. RSC Advances, 5(44), 35107-35115. https://doi.org/10.1039/C5RA04416B

Ghani, W. A. W. A. K., Mohd, A., da Silva, G., Bachmann, R. T., Taufiq-Yap, Y. H., Rashid, U., & Al-Muhtaseb, A. A. H. (2013). Biochar production from waste rubber-wood-sawdust and its potential use in C sequestration: Chemical and physical characterization. Industrial Crops and Products, 44, 18-24. https://doi.org/https://doi.org/10.1016/j.indcrop.2012.10.017

Ho, Y.-S. (2006a). Review of second-order models for adsorption systems. Journal of Hazardous Materials, 136(3), 681-689. https://doi.org/https://doi.org/10.1016/j.jhazmat.2005.12.043

Ho, Y. S. J. P. J. o. E. S. (2006b). Isotherms for the Sorption of Lead onto Peat: Comparison of Linear and Non-Linear Methods, 15, 81-86.

Inyang, M. I., Gao, B., Yao, Y., Xue, Y., Zimmerman, A., Mosa, A., ... & Cao, X. (2016). A review of biochar as a low-cost adsorbent for aqueous heavy metal removal. Critical Reviews in Environmental Science and Technology, 46(4), 406-433.

Kalderis, D., Koutoulakis, D., Paraskeva, P., Diamadopoulos, E., Otal, E., Valle, J. O. D., & Fernández-Pereira, C. (2008). Chemical Engineering Journal, 144(1), 42-50. https://doi.org/https://doi.org/10.1016/j.cej.2008.01.007

Kishida, M., Imamura, K., Takenaka, N., Maeda, Y., Viet, P. H., Kondo, A., & Bandow, H. (2010). Characteristics of the abundance of polychlorinated dibenzo-p-dioxin and dibenzofurans, and dioxin-like polychlorinated biphenyls in sediment samples from selected Asian regions in Can Gio, Southern Vietnam and Osaka, Japan. Chemosphere, 78(2), 127-133. https://doi.org/https://doi.org/10.1016/j.chemosphere.2009.10.003

Kumar, K. V., & Sivanesan, S. (2006). Pseudo second order kinetics and pseudo isotherms for malachite green onto activated carbon: Comparison of linear and non-linear regression methods. Journal of Hazardous Materials, 136(3), 721-726. https://doi.org/https://doi.org/10.1016/j.jhazmat.2006.01.003

Smirnov, A. D., Schecter, A., Päpke, O., & Beljak, A. A. (1996). Conclusions from Ufa, Russia, drinking water dioxin cleanup experiments involving different treatment technologies. Chemosphere, 32(3), 479-489. https://doi.org/https://doi.org/10.1016/0045-6535(95)00235-9

Tovar, C., Villabona-Ortíz, Á., & González-Delgado, A. (2021). Removal of Nitrate Ions Using Thermally and Chemically Modified Bioadsorbents. Applied Sciences, 11, 8455. https://doi.org/10.3390/app11188455

Vallejo, M., Fresnedo San Román, M., Ortiz, I., & Irabien, A. (2015). Overview of the PCDD/Fs degradation potential and formation risk in the application of advanced oxidation processes (AOPs) to wastewater treatment. Chemosphere, 118, 44-56. https://doi.org/10.1016/j.chemosphere.2014.05.077

Vimal, V., Patel, M., & Mohan, D. (2019). Aqueous carbofuran removal using slow pyrolyzed sugarcane bagasse biochar: equilibrium and fixed-bed studies [10.1039/C9RA01628G]. RSC Advances, 9(45), 26338-26350. https://doi.org/10.1039/C9RA01628G

Wang, J., & Guo, X. (2020). Adsorption kinetic models: Physical meanings, applications, and solving methods. Journal of Hazardous Materials, 390, 122156. https://doi.org/https://doi.org/10.1016/j.jhazmat.2020.122156

Wang, T., Zhang, D., Fang, K., Zhu, W., Peng, Q., & Xie, Z. (2021). Enhanced nitrate removal by physical activation and Mg/Al layered double hydroxide modified biochar derived from wood waste: Adsorption characteristics and mechanisms. Journal of Environmental Chemical Engineering, 9(4), 105184. https://doi.org/https://doi.org/10.1016/j.jece.2021.105184

Wang, T., Zheng, J., Liu, H., Peng, Q., Zhou, H., & Zhang, X. (2021). Adsorption characteristics and mechanisms of Pb2+ and Cd2+ by a new agricultural waste–Caragana korshinskii biomass derived biochar. Environmental Science and Pollution Research, 28(11), 13800-13818. https://doi.org/10.1007/s11356-020-11571-9

Yaashikaa, P. R., Kumar, P. S., Varjani, S., & Saravanan, A. (2020). A critical review on the biochar production techniques, characterization, stability and applications for circular bioeconomy. Biotechnology Reports, 28, e00570. https://doi.org/https://doi.org/10.1016/j.btre.2020.e00570

Ying, G.-G., Rawson, C. A., Kookana, R. S., Peng, P.-A., Warne, M. S. J., Tremblay, L. A., & Lim, R. P. (2009). Contamination and screening level toxicity of sediments from remediated and unremediated wetlands near Sydney, Australia [https://doi.org/10.1897/09-027.1]. Environmental Toxicology and Chemistry, 28(10), 2052-2060. https://doi.org/https://doi.org/10.1897/09-027.1

Zhang, L., Tong, L., Zhu, P., Huang, P., Tan, Z., Qin, F., … & Huang, H. (2018). Adsorption of chlortetracycline onto biochar derived from corn cob and sugarcane bagasse. Water Science and Technology, 78(6), 1336-1347. https://doi.org/10.2166/wst.2018.407

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