Al2TiO5/SBA-15 promoting photocatalytic degradation of cinnamic acid

Nguyen Dien Trung * , Nguyen Thi Hong , Mai Van Hieu and Nguyen Thanh Nhuan

* Corresponding author (ndtrung@ctu.edu.vn)

Article Sidebar

Full Text: PDF

Received: 04 Mar 2020
Revised: 13 Apr 2020
Accepted: 31 Jul 2020
Published: 31 Jul 2020
DOI: 10.22144/ctu.jen.2020.015
Views
241
Downloads
99
Crossref
Scopus
Google Scholar
Europe PMC
How to Cite
Nguyen, D. T., Nguyen, T. H., Mai, V. H., & Nguyen, T. N. (2020). Al2TiO5/SBA-15 promoting photocatalytic degradation of cinnamic acid. CTU Journal of Innovation and Sustainable Development , 12(2), 45-52. https://doi.org/10.22144/ctu.jen.2020.015
Issue
Vol. 12 No. 2 (2020)
Section
Natural Sciences

Main Article Content

Abstract

The synthesis of Al2TiO5/SBA-15 (ATO/SBA) catalysts was investigated by the sol-gel method using precursors including aluminum nitrate, titanium isopropoxide, SBA-15, and citric acid. The formation of ATO/SBA phases was analyzed by X-ray diffraction (XRD). The content of ATO in ATO/SBA catalysts strongly affected the photocatalytic degradation of cinnamic acid (CA). The obtained results showed that 75% ATO in ATO/SBA (75ATO/SBA ) phases led to the highest efficiency of CA photodegradation. The characteristics of 75ATO/SBA sample were determined by Fourier transform infrared spectroscopy, Brunauer-Emmett-Teller adsorption, UV-Vis diffuse reflectance spectroscopy, and transmission electron microscopy. Moreover, the activity of 75ATO/SBA on photocatalytic degradation of CA was also investigated by catalyst dosage, initial pH of CA solution, and airflow rate. The optimum condition for photodegradation efficiency of CA was found to be at Ccat = 0.75 g/L, pH = 3.8, Qair = 0.3 L/min and treact = 6 hrs.
Keywords: Cinnamic acid, degradation, mesoporous silica material, photocatalyst, pseudobrookite

Article Details

Creative Commons License

This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.

References

Aranda, A., Puértolas, B., Solsona, B., et al., 2010. Total oxidation of naphthalene using mesoporous CeO2 catalysts synthesized by nanocasting from two dimensional SBA-15 and three dimensional KIT-6 and MCM-48 silica templates. Catalysis Letters. 134(1): 110-117.

Assémian, A.S., Kouassi, K.E., Drogui, P., Adouby, K. and Boa, D., 2018. Removal of a persistent dye in aqueous solutions by electrocoagulation process: Modeling and optimization through response surface methodology. Water, Air, & Soil Pollution. 229(6): 184.

Azarniya, A., Azarniya, A., Hosseini, H.R.M. and Simchi, A., 2015. Nanostructured aluminium titanate (Al2TiO5) particles and nanofibers: Synthesis and mechanism of microstructural evolution. Materials Characterization. 103: 125-132.

Bakhshandeh, F., Azarniya, A., Madaah Hosseini H.R. and Jafari S., 2018. Are aluminum titanate-based nanostructures new photocatalytic materials? Possibilities and perspectives. Journal of Photochemistry and Photobiology A: Chemistry. 353: 316-324.

Bardestani R., Patience G.S. and Kaliaguine S., 2019. Experimental methods in chemical engineering: specific surface area and pore size distribution measurements-BET, BJH, and DFT. The Canadian Journal of Chemical Engineering. 97(11): 2781-2791.

Brillas E. and Martínez-Huitle C.A., 2015. Decontamination of wastewaters containing synthetic organic dyes by electrochemical methods. An updated review. Applied Catalysis B: Environmental. 166-167: 603-643.

dos Santos S.M.L., Nogueira K.A.B., de Souza Gama M., Lima J.D.F., da Silva Júnior I.J. and de Azevedo D.C.S., 2013. Synthesis and characterization of ordered mesoporous silica (SBA-15 and SBA-16) for adsorption of biomolecules. Microporous and Mesoporous Materials. 180: 284-292.

Dutta A., Chakraborty I., Sarkar D. and Chakrabarti S., 2015. Sunlight-assisted photo-Fenton degradation of pesticide in wastewater: Ecotoxicological impact on Nostoc sp. Algae. Water, Air, & Soil Pollution. 226(12): 398.

Georgaki I., Vasilaki E. and Katsarakis N., 2014. A study on the degradation of carbamazepine and ibuprofen by TiO2 and ZnO photocatalysis upon UV/Visible-light irradiation. American Journal of Analytical Chemistry. 05: 518-534.

Jin Q., Qu F., Jiang J., Dong Y., Guo W. and Lin H., 2013. A pH-sensitive controlled dual-drug release from meso-macroporous silica/multilayer-polyelectrolytes coated SBA-15 composites. Journal of Sol-Gel Science and Technology. 66(3): 466-471.

Kakavandi B., Takdastan A., Pourfadakari S., Ahmadmoazzam M. and Jorfi S., 2019. Heterogeneous catalytic degradation of organic compounds using nanoscale zero-valent iron supported on kaolinite: Mechanism, kinetic and feasibility studies. Journal of the Taiwan Institute of Chemical Engineers. 96: 329-340.

Kalantary R.R., Dadban Shahamat Y., Farzadkia M., Esrafili A. and Asgharnia H., 2015. Photocatalytic degradation and mineralization of diazinon in aqueous solution using nano-TiO2(Degussa, P25): kinetic and statistical analysis. Desalination and Water Treatment. 55(2): 555-563.

Keyvani N., Azarniya A., Hosseini H.R.M., Abedi M. and Moskovskikh D., 2019. Thermal stability and strain sensitivity of nanostructured aluminum titanate (Al2TiO5). Materials Chemistry and Physics. 223: 202-208.

Khin M.M., Nair A.S., Babu V.J., Murugan R. and Ramakrishna S., 2012. A review on nanomaterials for environmental remediation. Energy & Environmental Science. 5(8): 8075-8109.

Lam S.M., Sin J.C. and Mohamed A.R., 2010. Parameter effect on photocatalytic degradation of phenol using TiO2-P25/activated carbon (AC). Korean Journal of Chemical Engineering. 27(4): 1109-1116.

Li H., Zhu J., Xiao P., Zhan Y., Lv K., Wu L. and Li M., 2016. On the mechanism of oxidative degradation of rhodamine B over LaFeO3 catalysts supported on silica materials: Role of support. Microporous and Mesoporous Materials. 221: 159-166.

Madureira J., Barros L., Melo R., Cabo Verde S., Ferreira I.C.F.R. and Margaça F.M.A., 2018. Degradation of phenolic acids by gamma radiation as model compounds of cork wastewaters. Chemical Engineering Journal. 341: 227-237.

Malik R., Duhan S., Nehra S. and Rana P., 2015. Effect of annealing temperature on the photocatalytic performance of SnO2 nanoflowers towards degradation of Rhodamine B. Advanced Science. 7: 448-456.

Mojet B.L., Ebbesen S.D. and Lefferts L., 2010. Light at the interface: the potential of attenuated total reflection infrared spectroscopy for understanding heterogeneous catalysis in water. Chemical Society Reviews. 39(12): 4643-4655.

Pirilä M., Saouabe M., Ojala S.,et al., 2015. Photocatalytic degradation of organic pollutants in wastewater. Topics in Catalysis. 58(14): 1085-1099.

Phan T.T.N., Nikoloski A.N., Bahri P.A. and Li D., 2018. Adsorption and photo-Fenton catalytic degradation of organic dyes over crystalline LaFeO3-doped porous silica. RSC Advances. 8(63): 36181-36190.

Reddy C.V., Babu B., Reddy I.N. and Shim J., 2018. Synthesis and characterization of pure tetragonal ZrO2 nanoparticles with enhanced photocatalytic activity. Ceramics International. 44(6): 6940-6948.

Rovani S., Censi M.T., Pedrotti S.L., Lima É.C., Cataluña R. and Fernandes A.N., 2014. Development of a new adsorbent from agro-industrial waste and its potential use in endocrine disruptor compound removal. Journal of Hazardous Materials. 271: 311-320.

Thielemann J.P., Girgsdies F., Schlögl R. and Hess C., 2011. Pore structure and surface area of silica SBA-15: influence of washing and scale-up. Beilstein Journal of Nanotechnology. 2: 110-118.

Wu Q., Zhao L., Song R. and Ma A., 2019. Research progress of surfactant biodegradation. IOP Conference Series: Earth and Environmental Science. 227: 052023.

Yao Q., Lu Z.H., Yang K., Chen X. and Zhu M., 2015. Ruthenium nanoparticles confined in SBA-15 as highly efficient catalyst for hydrolytic dehydrogenation of ammonia borane and hydrazine borane. Scientific Reports. 5(1): 15186.

Zeng J., He B., Lamb K., De Marco R., Shen P.K. and Jiang S.P., 2013. Phosphoric acid functionalized pre-sintered meso-silica for high temperature proton exchange membrane fuel cells. Chemical Communications. 49(41): 4655-4657.