Main Article Content
Multifunctional materials have become one of the most interesting research subjects in recent years. Hydroxylapatite (HAp) coating on the surface of iron oxide (Fe3O4) nanoparticles allow to obtain material with adsorbable and magnetic properties. This study aims to salvage recycled eggshell to successfully produce adsorbent nanoparticles and evaluate treatment ability of methylene blue (MB) dyes in water. The magnetic nanomaterial was synthesized by a simple and inexpensive method. The X-ray diffraction technique was employed to characterize the structure of nanoparticles. The as-synthesized nanoparticles were analyzed by Fourier transform infrared spectroscopy technique to determine the presence of functional groups and bonds in the molecule. The surface morphology of as-synthesized Fe3O4/HAp nanoparticles was studied by transmission electron microscopy. The magnetic properties of Fe3O4 nanoparticles and Fe3O4/HAp nanoparticles were evaluated by vibrating sample magnetometer technique. The typical synthesized-HAp were dispersed rod-like particles with about 10 nm in width and 50 nm in length, the other part of final material was dispersed in spherical shape and their magnetism was 16.2 emu.g-1. The adsorption of MB was conducted with 89.6% yield at
This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.
Abidin, N. H. Z., Sambudi, N. S., & Kamal, N. A. (2020). Composite of Hydroxyapatite-Fe3O4 for the Adsorption of Methylene Blue. ASEAN Journal of Chemical Engineering, 20(2), 140-153.
Allam, K., El Bouari, A., Belhorma, B., & Bih, L. (2016). Removal of methylene blue from water using hydroxyapatite submitted to microwave irradiation. Journal of Water Resource and Protection, 8(3), 358-371.
Barka, N., Qourzal, S., Assabbane, A., Nounah, A., & Yhya, A.-I. (2008). Adsorption of Disperse Blue SBL dye by synthesized poorly crystalline hydroxyapatite. Journal of Environmental Sciences, 20(10), 1268-1272.
Bouyarmane, H., El Asri, S., Rami, A., Roux, C., Mahly, M., Saoiabi, A., . . . Laghzizil, A. (2010). Pyridine and phenol removal using natural and synthetic apatites as low cost sorbents: influence of porosity and surface interactions. Journal of Hazardous Materials, 181(1-3), 736-741.
Chaki, S., Malek, T. J., Chaudhary, M., Tailor, J., & Deshpande, M. (2015). Magnetite Fe3O4 nanoparticles synthesis by wet chemical reduction and their characterization. Advances in Natural Sciences: Nanoscience and Nanotechnology, 6(3), 035009.
Corami, A., Mignardi, S., & Ferrini, V. (2008). Cadmium removal from single-and multi-metal (Cd+ Pb+ Zn+ Cu) solutions by sorption on hydroxyapatite. Journal of colloid and interface science, 317(2), 402-408.
Dâas, A., & Hamdaoui, O. (2010). Extraction of anionic dye from aqueous solutions by emulsion liquid membrane. Journal of Hazardous Materials, 178(1-3), 973-981.
El-Gohary, F., & Tawfik, A. (2009). Decolorization and COD reduction of disperse and reactive dyes wastewater using chemical-coagulation followed by sequential batch reactor (SBR) process. Desalination, 249(3), 1159-1164.
El-Naas, M. H., Al-Muhtaseb, S. A., & Makhlouf, S. (2009). Biodegradation of phenol by Pseudomonas putida immobilized in polyvinyl alcohol (PVA) gel. Journal of Hazardous Materials, 164(2-3), 720-725.
Gergely, G., Wéber, F., Lukács, I., Tóth, A. L., Horváth, Z. E., Mihály, J., & Balázsi, C. (2010). Preparation and characterization of hydroxyapatite from eggshell. Ceramics international, 36(2), 803-806.
Gomes, H. T., Machado, B. F., Ribeiro, A., Moreira, I., Rosário, M., Silva, A. M., . . . Faria, J. L. (2008). Catalytic properties of carbon materials for wet oxidation of aniline. Journal of Hazardous Materials, 159(2-3), 420-426.
Gu, L., He, X., & Wu, Z. (2014). Mesoporous Fe3O4/hydroxyapatite composite for targeted drug delivery. Materials Research Bulletin, 59, 65-68.
Han, R., Li, W., Pan, W., Zhu, M., Zhou, D., & Li, F.-s. (2014). 1D magnetic materials of Fe 3 O 4 and Fe with high performance of microwave absorption fabricated by electrospinning method. Scientific reports, 4(1), 1-5.
Hu, J., Chen, G., & Lo, I. M. (2005). Removal and recovery of Cr (VI) from wastewater by maghemite nanoparticles. Water research, 39(18), 4528-4536.
Hu, J., Lo, I., & Chen, G. (2004). Removal of Cr (VI) by magnetite. Water Science and Technology, 50(12), 139-146.
Kim, J., Sambudi, N. S., & Cho, K. (2019). Removal of Sr2+ using high-surface-area hydroxyapatite synthesized by non-additive in-situ precipitation. Journal of environmental management, 231, 788-794.
Li, Y., Zhang, Y., Wang, G., Li, S., Han, R., & Wei, W. (2018). Reed biochar supported hydroxyapatite nanocomposite: Characterization and reactivity for methylene blue removal from aqueous media. Journal of Molecular Liquids, 263, 53-63.
Lin, K., Pan, J., Chen, Y., Cheng, R., & Xu, X. (2009). Study the adsorption of phenol from aqueous solution on hydroxyapatite nanopowders. Journal of Hazardous Materials, 161(1), 231-240.
Liu, J., Ye, X., Wang, H., Zhu, M., Wang, B., & Yan, H. (2003). The influence of pH and temperature on the morphology of hydroxyapatite synthesized by hydrothermal method. Ceramics international, 29(6), 629-633.
Ma, M., Zhang, Y., Yu, W., Shen, H.-y., Zhang, H.-q., & Gu, N. (2003). Preparation and characterization of magnetite nanoparticles coated by amino silane. Colloids and Surfaces A: physicochemical and engineering aspects, 212(2-3), 219-226.
Manatunga, D. C., de Silva, R. M., de Silva, K. N., de Silva, N., Bhandari, S., Yap, Y. K., & Costha, N. P. (2017). pH responsive controlled release of anti-cancer hydrophobic drugs from sodium alginate and hydroxyapatite bi-coated iron oxide nanoparticles. European Journal of Pharmaceutics and Biopharmaceutics, 117, 29-38.
Nga, N. K., Chau, N. T. T., & Viet, P. H. (2018). Facile synthesis of hydroxyapatite nanoparticles mimicking biological apatite from eggshells for bone-tissue engineering. Colloids and Surfaces B: Biointerfaces, 172, 769-778.
Nhu, L. T. Q. (2021). Synthesis of magnatic nanoparticles Fe3O4@HAp with HA derived from blood cockle's shell and its application for Cr(VI) adsorption from synthetic wastewater. Can Tho University, College of Engineering Technology.
Oliveira, L. C., Petkowicz, D. I., Smaniotto, A., & Pergher, S. B. (2004). Magnetic zeolites: a new adsorbent for removal of metallic contaminants from water. Water research, 38(17), 3699-3704.
Oubagha, N., Lemlikchi, W., Sharrock, P., Fiallo, M., & Mecherri, M. O. (2017). Hydroxyapatite precipitation with Hydron Blue dye. Journal of environmental management, 203, 807-810.
Rahimian, R., & Zarinabadi, S. (2020). A review of studies on the removal of methylene blue dye from industrial wastewater using activated carbon adsorbents made from almond bark. Progress in Chemical and Biochemical Research, 3(3), 251-268.
Saruchi, Thakur, P., & Kumar, V. (2019). Kinetics and thermodynamic studies for removal of methylene blue dye by biosynthesize copper oxide nanoparticles and its antibacterial activity. Journal of Environmental Health Science and Engineering, 17(1), 367-376. doi:10.1007/s40201-019-00354-1
Sharma, P., & Das, M. R. (2013). Removal of a cationic dye from aqueous solution using graphene oxide nanosheets: investigation of adsorption parameters. Journal of Chemical & Engineering Data, 58(1), 151-158.
Shin, S., & Jang, J. (2007). Thiol containing polymer encapsulated magnetic nanoparticles as reusable and efficiently separable adsorbent for heavy metal ions. Chemical communications(41), 4230-4232.
Tanaka, H., Tsuda, E., Nishikawa, H., & Fuji, M. (2012). FTIR studies of adsorption and photocatalytic decomposition under UV irradiation of dimethyl sulfide on calcium hydroxyapatite. Advanced Powder Technology, 23(1), 115-119.
Thanh, L. H. V., Han, K. G., Han, N. N., Pha, B. Y., & Ngoc, M. N. T. (2021). Tổng hợp vật liệu Fe3O4@ SiO2 đính Fe0 và xử lý methyl blue trong nước. Tạp chí Khoa học Trường Đại học Cần Thơ, 57(4), 40-52.
Thien, D. V. H., Thuyen, N. T. B., Quyen, T. T. B., Chiem, N. H., & Viet, P. H. (2021). Microwave-assisted synthesis of nanorod hydroxyapatite from eggshells. Vietnam Journal of Science, Technology and Engineering, 63(1), 3-6.
Vučinić-Vasić, M., Antić, B., Bošković, M., Antić, A., & Blanuša, J. (2019). Hydroxyapatite/iron oxide nanocomposite prepared by high energy ball milling. Processing and Application of Ceramics, 13(2), 210-217.
Wu, T., Cai, X., Tan, S., Li, H., Liu, J., & Yang, W. (2011). Adsorption characteristics of acrylonitrile, p-toluenesulfonic acid, 1-naphthalenesulfonic acid and methyl blue on graphene in aqueous solutions. Chemical Engineering Journal, 173(1), 144-149.
Yang, S., Zeng, T., Li, Y., Liu, J., Chen, Q., Zhou, J., . . . Tang, B. (2015). Preparation of graphene oxide decorated Fe3O4@ SiO2 nanocomposites with superior adsorption capacity and SERS detection for organic dyes. Journal of Nanomaterials, 2015.
Yang, Z.-p., Gong, X.-y., & Zhang, C.-j. (2010). Recyclable Fe3O4/hydroxyapatite composite nanoparticles for photocatalytic applications. Chemical Engineering Journal, 165(1), 117-121.
Yavuz, C. T., Mayo, J., William, W. Y., Prakash, A., Falkner, J. C., Yean, S., . . . Tomson, M. (2006). Low-field magnetic separation of monodisperse Fe3O4 nanocrystals. science, 314(5801), 964-967.
Zheltova, V., Vlasova, A., Bobrysheva, N., Abdullin, I., Semenov, V., Osmolowsky, M., . . . Osmolovskaya, O. (2020). Fe3O4@ HAp core–shell nanoparticles as MRI contrast agent: Synthesis, characterization and theoretical and experimental study of shell impact on magnetic properties. Applied Surface Science, 531, 147352.