Quoc-Phong Ho * , Hoang-Nam Truong , Phuc-Thong Lam , Bich-Thuyen Nguyen Thi , Van-Dung Nguyen , Pham Huu Ha-Giang and Lien-Huong Huynh

* Corresponding author (hqphong@ctu.edu.vn)

Main Article Content

Abstract

This study was carried out to optimize the treatment process of methyl blue (MB) in aqueous solution using dielectric barrier discharge (DBD) plasma and experiments were designed by using response surface methodology and central composite design (RSM-CCD). Four independent factors such as plasma power, liquid flow rate, air flow rate, and exposure time were investigated. According to the analyzed results of RSM, the experimental data is best fitted with a model of the quadratic polynomial with regression coefficient values of more than 0.9 for all responses. At optimal degradation conditions, the plasma power, liquid flow rate, air flow rate, and exposure time were 100 W, 1.5 lpm, 6 lpm, and 108.8 minutes respectively and the concentration of methyl blue was reduced to 95.8% with a concentration of 1.06 ppm. The degradation of methyl blue followed kinetic reaction rate was r = 1.6 10-3[MB]2.2.

Keywords: Degradation percentage, methyl blue, non-thermal DBD plasma, response surface methodology

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References

Abedi, K., Ghorbani-Shahna, F., Jaleh, B., Bahrami, A., Yarahmadi, R., Haddadi, R., & Gandomi, M. (2015). Decomposition of chlorinated volatile organic compounds (CVOCs) using NTP coupled with TiO2/GAC, ZnO/GAC, and TiO2–ZnO/GAC in a plasma-assisted catalysis system. Journal of Electrostatics, 73, 80-88.

Amiri, A., & Sabour, M. R. (2014). Multi-response optimization of Fenton process for applicability assessment in landfill leachate treatment. Waste Management, 34(12), 2528-2536.

Bai, Y., Chen, J., Yang, Y., Guo, L., & Zhang, C. (2010). Degradation of organophosphorus pesticide induced by oxygen plasma: effects of operating parameters and reaction mechanisms. Chemosphere, 81(3), 408-414.

Bansode, A. S., More, S. E., Siddiqui, E. A., Satpute, S., Ahmad, A., Bhoraskar, S. V., & Mathe, V. L. (2017). Effective degradation of organic water pollutants by atmospheric non-thermal plasma torch and analysis of degradation process. Chemosphere, 167, 396-405.

Bogaerts, A., Neyts, E., Gijbels, R., & Van der Mullen, J. (2002). Gas discharge plasmas and their applications. Spectrochimica Acta Part B: Atomic Spectroscopy, 57(4), 609-658.

Braithwaite, N. S. J. (2000). Introduction to gas discharges. Plasma Sources Science and Technology, 9(4), 517.

Capocelli, M., Joyce, E., Lancia, A., Mason, T. J., Musmarra, D., & Prisciandaro, M. (2012). Sonochemical degradation of estradiols: incidence of ultrasonic frequency. Chemical Engineering Journal, 210, 9-17.

De Moraes, S. G., Freire, R. S., & Duran, N. (2000). Degradation and toxicity reduction of textile effluent by combined photocatalytic and ozonation processes. Chemosphere, 40(4), 369-373.

Glaze, W. H., Kang, J.-W., & Chapin, D. H. (1987). The chemistry of water treatment processes involving ozone, hydrogen peroxide and ultraviolet radiation. Ozone: Science and Engineering, 9, 335-352.

Hemmert, D., Shiraki, K., Yokoyama, T., Katsuki, S., Bluhm, H., & Akiyama, H. (2003). Optical diagnostics of shock waves generated by a pulsed streamer discharge in water. Paper presented at the Digest of Technical Papers. PPC-2003. 14th IEEE International Pulsed Power Conference (IEEE Cat. No. 03CH37472).

Huang, F., Chen, L., Wang, H., Feng, T., & Yan, Z. (2012). Degradation of methyl orange by atmospheric DBD plasma: Analysis of the degradation effects and degradation path. Journal of Electrostatics, 70(1), 43-47.

Jiang, B., Zheng, J., Qiu, S., Wu, M., Zhang, Q., Yan, Z., & Xue, Q. (2014). Review on electrical discharge plasma technology for wastewater remediation. Chemical Engineering Journal, 236, 348-368.

Kogelschatz, U. (2003). Dielectric-barrier discharges: their history, discharge physics, and industrial applications. Plasma Chemistry Plasma Processing, 23(1), 1-46.

Kuraica, M., Obradović, B., Manojlović, D., Ostojić, D., & Purić. (2006). Application of coaxial dielectric barrier discharge for potable and waste water treatment. Ind. Eng. Chem. Res., 45, 882-905.

Li, H., Fei, G. T., Fang, M., Cui, P., Guo, X., Yan, P., & De Zhang, L. (2011). Synthesis of urchin-like Co3O4 hierarchical micro/nanostructures and their photocatalytic activity. Applied Surface Science, 257(15), 6527-6530.

Li, X., Wang, L., & Wang, B. (2017). Optimization of encapsulation efficiency and average particle size of Hohenbuehelia serotina polysaccharides nanoemulsions using response surface methodology. Food Chemistry, 229, 479-486.

Locke, B., Sato, M., Sunka, P., Hoffmann, M., & Chang, J.-S. (2006). Electrohydraulic discharge and nonthermal plasma for water treatment. Industrial Engineering Chemistry Research, 45(3), 882-905.

Myers, R. H., Montgomery, D. C., & Anderson-Cook, C. M. (2016). Response surface methodology: process and product optimization using designed experiments. New York: John Wiley & Sons.

Quanhong, L., & Caili, F. (2005). Application of response surface methodology for extraction optimization of germinant pumpkin seeds protein. Food Chemistry, 92(4), 701-706.

Qutub, N., Pirzada, B. M., Umar, K., & Sabir, S. (2016). Synthesis of CdS nanoparticles using different sulfide ion precursors: formation mechanism and photocatalytic degradation of Acid Blue-29. Journal of Environmental Chemical Engineering, 4(1), 808-817.

Reddy, P. M. K., Raju, B. R., Karuppiah, J., Reddy, E. L., & Subrahmanyam, C. (2013). Degradation and mineralization of methylene blue by dielectric barrier discharge non-thermal plasma reactor. Chemical Engineering Journal, 217, 41-47.

Schriver, D., Ashour-Abdalla, M., & Richard, R. L. (1998). On the origin of the ion‐electron temperature difference in the plasma sheet. Journal of Geophysical Research: Space Physics, 103(A7), 14879-14895.

Wang, H., Guo, H., Wu, Q., Zhou, G., & Yi, C. (2016). Effect of activated carbon addition on H2O2 formation and dye decoloration in a pulsed discharge plasma system. Vacuum, 128, 99-105.

Wang, L., Yu, Z., Peng, Z., Chen, Y., Xiang, G., Liu, Q., . . . Chen, D. (2016). Catalytic properties of TiO2/Fe3O4 nanoparticles in plasma chemical treatment. Russian Journal of Physical Chemistry A, 90(4), 777-782.

Wardenier, N. (2016). Non-equilibrium plasma in contact with water as advanced oxidation process for decomposition of micro pollutants. (Master thesis). Gent University.

Xiang, Q., Yu, J., & Wong, P. K. (2011). Quantitative characterization of hydroxyl radicals produced by various photocatalysts. Journal of Colloid Interface Science, 357(1), 163-167.

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